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Solitons & polarons in conducting polymers /

Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original p...

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Bibliographic Details
Main Authors: Yu, Lu, 1937- (Author)
Corporate Authors: World Scientific (Firm)
Published: World Scientific Pub. Co.,
Publisher Address: Singapore ; Teaneck, N.J. :
Publication Dates: 1988.
Literature type: eBook
Language: English
Subjects:
Solitons.
Polarons.
Spectrum analysis.
Electronic books.
Online Access: http://www.worldscientific.com/worldscibooks/10.1142/0242#t=toc
Summary: Polyacetylence, (CH)x is the simplest conjugated polymer. Prestine polyacetylence is a good insulator, whereas its highly doped version exhibits metal-like electrical conductivity. This book gives a detailed introduction to this rapidly-developing field is given along with a collection of original papers. The main purpose is to help chemists and physicists grasp the main ideas and most important facts; an expert may also find it useful as a reference volume.
Carrier Form: 1 online resource (xv,754pages) : illustrations
Bibliography: Includes bibliographical references.
ISBN: 9789814503136
CLC: O413.1
Contents: pt. one. Introduction. I. Why solitons? -- II. Ground state configuration -- III. Soliton excitations -- IV. Polarons and bipolarons -- V. Soliton and polaron dynamics -- VI. Residual interactions -- VII. Optical properties -- VIII. Magnetic properties -- IX. Transport properties and metal-insulator transition -- X. Fractional charge and relation to quantum field theory -- pt. two. Reprinted papers. I. Why solitons? 1. Preparation and morphology of as-prepared and highly stretch-aligned polyacetylene / H. Shirakawa & S. Ikeda -- 2. Electrical conductivity in doped polyacetylene / C.K. Chiang ... [et al.] -- 3. Bond alternation defects in long polyene molecules / J.A. Pople & S.H. Walmsley -- 4. Magnetic susceptibility of doped polyacetylene / B.R. Weinberger ... [et al.] -- 5. Solitons in polyacetylene / W.P. Su, J.R. Schrieffer, and A.J. Heeger -- 6. Charged -phase kinks in lightly doped polyacetylene / M.J. Rice -- 7. Electronic excitations in the Peierls-Fr hlich state / S.A. Brazovskii -- II. Ground state configuration. 8. Structural determination of the symmetry breaking parameter in trans-(CH)x / C.R. Fincher ... [et al.] -- 9. Molecular geometry of cis- and trans-polyacetylene by nutation NMR spectroscop / C.S. Yannoni & T.C. Clarke -- 10. Self-consistent crystal potential and band structure of three-dimensional trans-polyacetylen / P.M. Grant & I.P. Batra -- III. Soliton excitations. 11. Soliton excitations in polyacetylene / W.P. Su, J.R. Schrieffer, and A.J. Heeger -- 12. Continuum model for solitons in polyacetylene / H. Takayama, Y.R. Lin-Liu, and K. Maki -- 13. Self-localized excitations in the Peierls-Fr hlich state / S.A. Brazovskii -- 14. Boundary conditions and optical absorption in the soliton model of polyacetylene / S. Kivelson ... [et al.] -- IV. Polarons and bipolarons. 15. Excitons, polarons and bipolarons in conducting polymers / S.A. Brazovskii & N. Kirova -- 16. Solitons in polyacetylene and the relativistic field theory model / D.K. Campbell & A.R. Bishop -- 17. Solitons and polarons in polyacetylene: self-consistent-field calculations of the effect of neutral and charged defects on molecular geometry / D.S. Boudreaux ... [et al.] -- 18. Bipolaron dynamics in nearly degenerate quasi-one-dimensional polymers / C.L. Wang, Z.B. Su, and F. Martino -- 19. Two-soliton interaction energy and the soliton lattice in polyacetylene / Y.R. Lin-Liu & K. Maki -- 20. Two-polaron solution and its stability in the continuum model of polyacetylene / Y. Onodera & S. Okuno -- 21. Polaron-bipolaron - soliton doping in polyacetylene / S. Stafstr m & K.A. Chao -- 22. Soliton lattice in polyacetylene, spin-Peierls systems, and two-dimensional sine-Gordon systems / B. Horovitz -- V. Soliton and polaron dynamics. 23. Vibrational excitations of charged solitons in polyacetylene / E.J. Mele & M.J. Rice -- 24. Infrared activity of Peierls systems and application to polyacetylene / B. Horovitz -- 25. Linear mode analysis around a soliton in trans-polyacetylene (CH)x / H. Ito ... [et al.] -- 26. Soliton dynamics in polyacetylene / W.P. Su & J.R. Schreiffer -- 27. Dynamics of polyacetylene chains / F. Guinea -- 28. Effect of quantum fluctuations on the Peierls instability: a Monte Carlo study / J.E. Hirsch & E. Fradkin -- 29. Theory of soliton generation and lattice relaxation in polyacetylene (i) general formalism / Z.B. Su & L. Yu -- 30. Quantum corrections to solitons in polyacetylene / M. Nakahara & K. Maki -- 31. Photoinduced soliton pair production in polyacetylene: an instanton approach / J.P. Sethna & S. Kivelson.
VI. Residual interactions. 32. Bond alternation, on-site Coulomb correlations, and solitons in polyacetylene / K.R. Subbaswamy & M. Grabowski -- 33. Correlation effects on bond alternation in polyacetylene / P. Horsch -- 34. Effect of Coulomb interactions on Peierls instability / J.E. Hirsch -- 35. Soliton energetics in Peierls-Hubbard models / D.K. Campbell, T.A. DeGrand, and S. Mazumdar -- 36. Optical excitations of even and odd polyenes with molecular PPP correlations / S. Ramasesha & Z.G. Soos -- 37. Theory of conducting polymers with weak electron-electron interactions / W.-K. Wu & S. Kivelson -- 38. Soliton confinement in polyacetylene due to interchain coupling / D. Baeriswyl and K. Maki -- VII. Optical properties. 39. Solitons in polyacetylene: effects of dilute doping on optical absorption spectra / N. Suzuki ... [et al.] -- 40. Opto-electrochemical spectroscopy of trans-(CH)x / A. Feldblum ... [et al.] -- 41. Optical absorption in polyacetylene: a direct measurement using photothermal deflection spectroscopy / B.R. Weinberger ... [et al.] -- 42. Infrared spectra of poly(acetylene) / H. Shirakawa & S. Ikeda -- 43. Donor and acceptor states in lightly doped polyacetylene, (CH)x / C.R. Fincher, Jr. ... [et al.] -- 44. Resonance Raman results in polyacetylene / D.B. Fitchen -- 45. Theoretical analysis of absorption and resonant Raman scattering spectra of trans-(CH)x / G.P. Brivio & E. Mulazzi -- 46. Resonant Raman scattering from amplitude modes in trans-(CH)x, and -(CD)x / Z. Vardeny ... [et al.] -- 47. Photoconductivity in polyacetylene / S. Etemad ... [et al.] -- 48. Picosecond photoconductivity in trans-polyacetylene / M. Sinclair, D. Moses, and A.J. Heeger -- 49. Excitation profile for photogeneration of solitons in trans-(CH)x / G.B. Blanchet, C.R. Fincher, and A.J. Heeger -- 50. Photoluminescence of cis- and trans-poly acetylene / K. Yoshino ... [et al.] -- 51. Photogenerated gap states in polyacetylene / J. Orenstein & G.L. Baker -- 52. Ultraviolet photoelectron spectroscopy of optically excited states in trans-polyacetylene / W.R. Salaneck ... [et al.] -- 53. Picosecond photoinduced dichroism in trans-(CH)x: direct measurement of soliton diffusion / Z. Vardeny ... [et al.] -- 54. Picosecond dynamics of photoexcited gap states in polyacetylene / C.V. Shank ... [et al.] -- 55. Photoexcitations in trans-(CH)x: a Fourier-transform infrared study / G.B. Blanchet ... [et al.] -- 56. Photoinduced infrared activity in polyacetylene / Z. Vardeny, J. Orenstein, and G.L. Baker -- 57. Photogeneration of solitons in trans-(CH)x: the reversed spin-charge relation of the photoexcitations / J.D. Flood & A.J. Heeger -- 58. Photoproduction of neutral versus charged solitons in trans-(CH)x / R. Ball, W.P. Su, and J.R. Schrieffer -- 59. Theory of soliton generation and lattice relaxation in polyacetylene (III) radiative transitions / Z.B. Su & L. Yu -- 60. Breathers and photoinduced absorption in polyacetylene / A.R. Bishop ... [et al.] -- 61. Photogeneration of confined soliton pairs (bipolarons) in polythiophene / Z. Vardeny ... [et al.].
VIII. Magnetic properties. 62. Electron spin resonance of polyacetylene and AsF[symbol] -doped polyacetylene / I.B. Goldberg ... [et al.] -- 63. Solitons in polyacetylene: magnetic susceptibility / S. Ikehata ... [et al.] -- 64. Electron spin resonance studies of magnetic soliton defects in polyacetylene / B.R. Weinberger ... [et al.] -- 65. Magnetic susceptibility of iodine doped polyacetylene: the effects of nonuniform doping / A.J. Epstein ... [et al.] -- 66. One-dimensional spin diffusion in polyacetylene, (CH)x / M. Nechtschein ... [et al.] -- 67. Spin dynamics at low temperature in undoped trans-polyacetylene, (CH)x / K. Holczer ... [et al.] -- 68. Absence of knight shift in the metallic state of polyacetylene / M. Peo ... [et al.] -- 69. [symbol]C high-resolution NMR study of doped polyacetylene / T. Terao ... [et al.] -- 70. Electron-nuclear double-resonance determination of the [symbol]C and [symbol]H hyperfine tensors for polyacetylene / H. Thomann ... [et al.] -- 71. Neutral solitons in polyacetylene: implications of the ENDOR results / A.J. Heeger & J.R. Schrieffer -- 72. Direct observation of "soliton-like" spin density distribution in undoped cis-rich (CH)x by ENDOR at 4 K / S. Kuroda, H. Bando, and H. Shirakawa -- IX. Transport properties and metal-insulator transition. 73. Electrical transport in doped polyacetylene / Y.W. Park ... [et al.] -- 74. Anomalous frequency-dependent conductivity of polyacetylene / A.J. Epstein ... [et al.] -- 75. Electron hopping conduction in the soliton model of polyacetylene / S. Kivelson -- 76. Solitons at high density in trans-(CH)x: collective transport by mobile, spinless, charged solitons / T.C. Chung ... [et al.] -- 77. Density of states and hopping conductivity in nearly metallic polyacetylene / A.J. Epstein ... [et al.] -- 78. The role of the Peierls instability in doped polyacetylene / M.J. Rice & E.J. Mele -- 79. Soliton lattice to metal: a first order phase transition / J. Chen ... [et al.] -- 80. First-order transition to a metallic state in polyacetylene: a strong-coupling polaronic metal / S. Kivelson & A.J. Heeger -- X. Fractional charge and relation to quantum field theory. 81. Solitons with fermion number 1/2 in condensed matter and relativistic field theories / R. Jackiw & J.R. Schrieffer -- 82. Fractionally charged excitations in quasi-one-dimensional systems / J.R. Schrieffer -- 83. Fractional quantum numbers on solitons / J. Goldstone & F. Wilczek -- 84. Elementary derivation of one-dimensional fermion-number fractionalization / M. Stone.

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