Screen LibrarySome problems of chemical kinetics and reactivity. Volume 1 /
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| Main Authors: | |
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| Corporate Authors: | |
| Published: |
Elsevier Science,
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| Publisher Address: | Burlington : |
| Publication Dates: | 1958. |
| Literature type: | eBook |
| Language: | English |
| Subjects: | |
| Online Access: |
http://www.sciencedirect.com/science/book/9781483167473 |
| Item Description: | 8. free radical production by reaction between stable molecules. |
| Carrier Form: | 1 online resource (674 pages) |
| ISBN: |
9781483194950 1483194957 |
| Index Number: | QD502 |
| CLC: | O643.1 |
| Contents: |
Cover image; Title page; Table of Contents; Copyright; INTRODUCTION; PART I: RADICAL REACTIONS (PROPAGATION AND BRANCHING OF CHAIN REACTIONS); Chapter 1: UNIRADICAL REACTIVITIES; Publisher Summary; 1. RADICAL REACTIONS: BASIC TYPES; 2. EXPERIMENTAL DETERMINATION OF ACTIVATION ENERGIES; 3. BOND DISSOCIATION ENERGIES; 4 THE CORRELATION OF ACTIVATION ENERGIES WITH HEATS OF REACTION; 5 RADICAL AND MOLECULAR ACTIVITIES; 6. EMPIRICAL FORMULAE FOR COMPUTING BOND-ENERGIES IN ORGANIC MOLECULES; 7. ADDITION AT MULTIPLE BONDS; 8. RADICAL DECOMPOSITION AND THE ENERGIES OF -BONDS. 9. RADICAL ISOMERIZATIONS10. TRANSFER REACTIONS; 11. POLAR FACTORS IN ORGANIC REACTIONS; 12. POLAR FACTORS IN POLYMERIZATION *; Chapter 2: ALTERNATIVE UNIVALENT FREE-RADICAL REACTIONS; Publisher Summary; 1 THE OCCURRENCE OF ALTERNATIVE RADICAL REACTIONS; 2. THE INFLUENCE OF TEMPERATURE AND PRESSURE ON ALTERNATIVE RADICAL REACTIONS; 3 INTERMEDIARY AND TERMINAL PRODUCTS IN CHAIN REACTIONS; Chapter 3: THE REACTIONS OF BIRADICALS; Publisher Summary; 1 THE TRANSITION OF ATOMS TO THE ACTIVE-VALENCE STATE; 2 REACTIVITY IN THE MOLECULES O2, S2 AND Se2; 3 DIVALENT CARBON; 4 COMPLEX BIRADICALS. 5 PRODUCTION AND REACTIVITY OF> CH2 AND -O-6 THE ROLE OF BIRADICALS IN CHAIN REACTIONS; PART II: INITIATION AND TERMINATION OF CHAIN REACTIONS; Chapter 4: MOLECULAR DISSOCIATION AND RADICAL COMBINATION; Publisher Summary; 1. HOMOGENEOUS INITIATION OF CHAINS; 2. HOMOGENEOUS RECOMBINATION OF RADICALS; 3. DEPENDENCE OF OVERALL REACTION KINETICS ON CHAIN-TERMINATION MECHANISM; 4. SPECIAL ASPECTS OF RADICAL GENERATION AND RECOMBINATION IN LIQUIDS; 5. THE EFFECTS OF INHIBITORS ON THE RATES OF CHAIN REACTIONS; Chapter 5: IONS OF VARIABLE VALENCY AS CHAIN INITIATORS; Publisher Summary. 1. FORMATION OF RADICALS AND IONIC RADICALS BY ELECTRON TRANSFER2. THERMODYNAMIC AND KINETIC ASPECTS OF FREE RADICAL FORMATION; 3. IONS OF VARIABLE VALENCY AS CHAIN INITIATORS; Chapter 6: WALL INITIATION AND RETARDATION OF CHAIN REACTIONS; Publisher Summary; 1. GENERATION AND REMOVAL OF FREE RADICALS AT THE VESSEL WALLS [1]; 2. THE METHOD OF DIFFERENTIAL CALORIMETRY; 3. FREE VALENCIES IN THE WALLS; 4. RADICAL PRODUCTION AT ACTIVE SURFACES; 5. HETEROGENEOUS PRODUCTION OF RADICALS WHEN GASEOUS ADMIXTURES ARE PRESENT; 6. HETEROGENEOUS MOLECULAR REACTIONS GIVING FREE RADICALS. 7. APPLICATION OF THE ABOVE CONCEPTS TO HETEROGENEOUS CATALYSIS8. HETEROGENEOUS CATALYSIS IN BIOLOGY; PART III: KINETICS OF CHAIN REACTIONS; Chapter 7: CHAIN REACTIONS COMPETING WITH REACTIONS BETWEEN SATURATED MOLECULES; Publisher Summary; 1. ENERGY DEPENDENCE OF CHAIN REACTIONS AND MOLECULAR REACTIONS; 2. THE RELATIVE RATES OF DIRECT MOLECULAR AND CHAIN REACTIONS; 3. ALKYL BROMIDE DECOMPOSITION; 4. ALKYL CHLORIDE DECOMPOSITION; 5. THE CRACKING OF HYDROCARBONS; 6. FACTORS INFLUENCING THE CHAIN LENGTH; 7. THE ELEMENTARY ACT OF DECOMPOSITION. |