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CH-acids : a guide to all existing problems of CH-acidity with new experimental methods and data, including indirect electrochemical, kinetic and thermodynamic studies /

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Bibliographic Details
Main Authors: Reutov, O. A. Oleg Aleksandrovich, 1920
Corporate Authors: Elsevier Science & Technology
Group Author: Crompton, T. R. ǂq Thomas Roy; Belet s kai a , I. P. Irina Petrovna; Butin, K. P
Published: Pergamon Press,
Publisher Address: Oxford [England] ; New York :
Publication Dates: 1978.
Literature type: eBook
Language: English
Russian
Subjects:
Organic acids
SCIENCE / Chemistry / Organic
Electronic books
Online Access: http://www.sciencedirect.com/science/book/9780080216102
Carrier Form: 1 online resource (viii, 228 pages) : illustrations
Bibliography: Includes bibliographical references and index.
ISBN: 9780080216102
0080216102
1483163830
9781483163833
Index Number: QD305
CLC: O621
Contents: Front Cover; Ch-Acids; Copyright Page; Table of Contents ; Preface; Chapter 1. Equilibrium Acidity of CH-Acids; I. Introduction; II. CH-Acidities in Water. A comparison with OH-Acids; III. Methods of Measuring Ionisation Equilibria of CH-Acids; Chapter 2. Structure Effects on Equilibrium CH-Acidity; I. Acidity in the Gas Phase; II. Acidity in Solution; Chapter 3. Kinetic CH-Acidity; I. Hydrogen Isotope Exchange. Protophilic Mechanism; II. Hydrogen Isotope Exchange Rates in CH-Acids of Various Types; III. Kinetic Isotope Effect and Exchange Mechanism
Chapter 4. Stereochemistry of Proton TransferI. Cyclopropane CH-Acids; II. Vinyl CH-Acids; III. CH-Acids with Substituents Containing Sulphur; IV. CH-Acids Forming Ambidental Anions; V. Fluorene CH-Acids; VI. Benzyl CH-Acids; VII. Proton Transfer Accompanied by Re-arrangements in Unsaturated Systems; Chapter 5. Relationship Between Equilibrium and Kinetic Acidity; I. Three-Step Proton Transfer Mechanism; II. Theoretical Interpretation of the Bro nsted Equation; III. ''Normal"" Bronsted Plots; IV. Correlations of Proton Transfer Rate with Acidity Function H-
V. Bronsted Plots with Anomalous SlopesVI. H2O/OH- System; VII. Conclusion; References; Index; Additional References for 1975 to 1978

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