Screen LibraryC-H activation for asymmetric synthesis/
Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the con...
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| Corporate Authors: | |
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| Group Author: | ; |
| Published: |
Wiley-VCH ,
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| Publisher Address: | Weinheim, Germany : |
| Publication Dates: | 2019 |
| Literature type: | eBook |
| Language: | English |
| Subjects: | |
| Online Access: |
https://onlinelibrary.wiley.com/doi/book/10.1002/9783527810857 |
| Summary: |
Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts - asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds - CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)-H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)-H bond activation; amongst other methods |
| Item Description: | Description based on print version record. |
| Carrier Form: |
1 online resource (xi, 281 pages) : illustrations Also available in print. |
| Bibliography: | Includes bibliographical references and index |
| ISBN: |
9783527810857 3527810854 9783527343409 |
| Index Number: | QD262 |
| CLC: | O621.3 |