Screen LibraryOrganomagnesium methods in organic synthesis /
The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium...
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| Main Authors: | |
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| Corporate Authors: | |
| Published: |
Academic Press,
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| Publisher Address: | London ; San Diego : |
| Publication Dates: | 1995. |
| Literature type: | eBook |
| Language: | English |
| Series: |
Best synthetic methods
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| Subjects: | |
| Online Access: |
http://www.sciencedirect.com/science/book/9780127309453 |
| Summary: |
The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as |
| Carrier Form: | 1 online resource (xvi, 249 pages) : illustrations. |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: |
9780127309453 0127309454 9780080538174 0080538177 |
| Index Number: | QD412 |
| CLC: | O621.3 |
| Contents: | Introduction and General References. General Considerations in the Application of Organomagnesium Compounds in Organic and Organometallic Synthesis. Preparation of Organomagnesium Compounds. Addition of Organomagnesium Compounds to Carbon-Carbon Multiple Bonds. Addition of Organomagnesium Compounds to Carbon-Nitrogen Multiple Bonds. Addition of Organomagnesium Compounds to Carbonyl Groups. Carbophilic Addition of Organomagnesium Compounds to Thiocarbonyl Groups. Substitution atCarbon by Organomagnesium Compounds. Carbenoid and Arynoid Reactions of Organomagnesium Compounds. Reactions of Orga |