Screen LibrarySolution thermodynamics and its application to aqueous solutions : a differential approach /
Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth...
Saved in:
| Main Authors: | |
|---|---|
| Corporate Authors: | |
| Published: |
Elsevier,
|
| Publisher Address: | Amsterdam : |
| Publication Dates: |
[2017] ©2017 |
| Literature type: | eBook |
| Language: | English |
| Edition: | Second edition. |
| Subjects: | |
| Online Access: |
https://www.sciencedirect.com/science/book/9780444636294 |
| Summary: |
Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach, Second Edition introduces a differential approach to solution thermodynamics, applying it to the study of aqueous solutions. This valuable approach reveals the molecular processes in solutions in greater depth than that gained by spectroscopic and other methods. The book clarifies what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. By applying the same methodology to ions that have been ranked by the Hofmeister series, the author shows that the kosmotropes are either hydrophobes or hydration centers, and that chaotropes are hydrophiles. This unique approach and important updates make the new edition a must-have reference for those active in solution chemistry. |
| Carrier Form: | 1 online resource : illustrations |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: |
9780444636300 0444636307 9780444636294 0444636293 |
| Index Number: | QD541 |
| CLC: | O645.16 |
| Contents: |
Front Cover; Solution Thermodynamics and its Application to Aqueous Solutions: A Differential Approach; Copyright; Dedication; Contents; Preface to the First Edition; Preface to the Second Edition; Acknowledgments for the First Edition; Acknowledgments for the Second Edition; Chapter 0: Introduction; [0-1]. Introduction; [0-2]. Qualitative Judgments and Sciences; [0-3]. Outline of This Book; Part A: A Differential Approach in Solution Thermodynamics; Chapter I: Basics of Thermodynamics-Derivatives of Gibbs Energy, G; [I-1]. System, State, the First, and Second Laws of Thermodynamics. [I-2]. Giles' Derivation of Entropy[I-2-1]. State, Process, and Irreversibility of Process; [I-2-2]. Entropy, and Potentials-Defining T, and p; [I-3]. Logical (Mathematical) Deduction; [I-4]. Stability Criteria; [I-5]. Multicomponent System-Partial Molar Quantities; [I-6]. Excess Quantities; [I-7]. Response Functions; [I-8]. Thermodynamic Quantities-Order of Derivative; [I-9]. Interaction Functions-Third Derivatives; Chapter II: Solution Thermodynamics-Use of the Second and Third Derivatives of G; [II-1]. Mixture; [II-2]. Gibbs-Duhem Relation; [II-3]. Vapor Pressures-Phase Equilibrium. [II-4]. Raoult's Law and Henry's Law[II-5]. Process of Mixing-Mixing Entropy; [II-6]. Conversion From (nB, nW) to (xB, N) Variable Systems; [II-7]. Interaction Functions Due to the Ideal Mixing Entropy; [II-8]. Phase Separation-Critical Point (UCST or LCST); [II-9]. Azeotrope; [II-10]. Phase Transitions; [II-10-1]. Introduction; [II-10-2]. Heat Capacity Anomalies for General Phase Transitions-Two Level Model With Mean-Field Approximation; Chapter III: Determination of the Second and Third Derivatives of G; [III-1]. Introduction; [III-2]. Calculation of HiE From HmE. [IV-2]. Fluctuation Functions-Coarse Grain[IV-3]. H2O vs n-Hexane; [IV-4]. Site-Correlated Percolation Model of Liquid H2O; [IV-5]. Concentration Fluctuations and Kirkwood-Buff Integrals; Part B: Studies of Aqueous Solutions Using the Second, the Third, and the Fourth Derivatives of G; Chapter V: Mixing Schemes in Aqueous Mono-ols; [V-1]. Mixing Schemes in 2-Butoxyethanol (BE)-H2O; [V-2]. Mixing Schemes on Other Mono-ols(AL)-H2O; [V-2-1]. Enthalpic and Entropic AL-AL Interactions, HAL-ALE and SAL-ALE; [V-2-2]. Volumetric AL-AL Interactions, VAL-ALE. |