Screen LibraryZiegler-Natta catalysts and polymerizations /
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| Main Authors: | |
|---|---|
| Corporate Authors: | |
| Published: |
Academic Press,
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| Publisher Address: | New York : |
| Publication Dates: | 1979. |
| Literature type: | eBook |
| Language: | English |
| Subjects: | |
| Online Access: |
http://www.sciencedirect.com/science/book/9780121155506 |
| Carrier Form: | 1 online resource (xvii, 670 pages) : illustrations |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: |
9780323143417 0323143415 |
| Index Number: | TP159 |
| CLC: | TQ314.24 |
| Contents: |
Front Cover; Ziegler-Natta Catalysts and Polymerizations; Copyright Page; Deditation; Table of Contents; Foreword; Preface; John Boor; CHAPTER1. HIGHLIGHTS OF ZIEGLER-NATTA CATALYSTS AND POLYMERIZATIONS; I. Highlights; II. Collected Reviews; References; CHAPTER 2. GENESIS OF ZIEGLER-NATTA CATALYSTS; I. Scientific and Commercial Importance; II. Historical Origins; III. Anticipation of the Catalyst and Contemporary Discoveries; IV. The Golden Age of Polymer Science; References; CHAPTER 3. DEFINITIONS, STEREOCHEMISTRY, EXPERIMENTAL METHODS, AND COMMERCIAL POLYMERS; I. Introduction. II. Definition of Ziegler-Natta CatalystsIII. Stereochemical Structures of Polymers and Methods of Characterization; IV. Experimental Methods; V. Commercial Polymers; References; CHAPTER 4. CHEMICAL DESCRIPTION OF ZIEGLER-NATTA CATALYSTS FOR OLEFINS; I. Introduction; II. Factors Determining Behavior of Catalysts for Olefins; III. Some Important Classes of Catalysts for Olefins; IV. Conclusion; References; CHAPTER 5. THE CHEMICAL DESCRIPTION OF CATALYSTS FOR CONJUGATED DIENES; I. Introduction; II. Factors Determining Isomerism; III. Important Catalysts Identified for Specific Conjugated Dienes. IV. ConclusionReferences; CHAPTER 6. INITIAL PHYSICAL STATE OF THE CATALYST; I. Introduction; II. Importance of the Physical State of the Catalyst; III. Soluble Catalyst; IV. Colloidal Catalysts; V. Heterogenous Catalysis Including Supported Types; VI. Conclusion; References; CHAPTER 7. PHYSICAL STATE OF THE POLYMER DURING POLYMERIZATION; I. Introduction; II. The Solution Process; III. The Slurry Process; IV. Vapor Phase Process; V. Conclusion; References; CHAPTER 8. GROWTH OF THE POLYMER PARTICLE; I. Introduction; II. Replication; III. Architecture of TiCl3 Particles. IV. How Does the Polymer Particle Grow?V. Practical Importance; VI. Conclusion; References; CHAPTER 9. MODIFICATION OF ZIEGLER-NATTA CATALYSTS BY THIRD COMPONENTS; I. Introduction; II. Discussion of Donors: Types of Third Components Added; III. Conclusion; References; CHAPTER 10. TERMINATION OF POLYMER CHAIN GROWTH; I. Introduction; II. Chain Termination by Organic and Inorganic Compounds; III. Chain Termination by Metal Alkyls; IV. Chain Termination by Molecular Hydrogen; V. Chain Termination by Unsaturated Hydrocarbons; VI. Chain Termination by Thermal Cleavage. VII. Chain Termination by Mechanical ForcesReferences; CHAPTER 11. OXIDATION STATE OF CATALYSTS AND ACTIVE CENTERS; I. Introduction; II. Catalysts Containing Selected Period 2 Transition Metal Salts; III. Conclusion; References; CHAPTER 12. METAL ALKYL-FREE CATALYSTS; I. Introduction; II. Phillips and Standard of Indiana Catalysts; III. Metal Alkyl-Free Catalysts Discovered after 1955; IV. Relationship to Ziegler-Natta Catalysts; References; CHAPTER 13. MECHANISMS FOR INITIATION AND PROPAGATION OF OLEFINS; I. Introduction; II. Nomenclature; III. Proposed Mechanisms; IV. Experimental Evidence. |