Ultrananocrystalline diamond : synthesis, properties and applications /
Ultrananocrystalline Diamond: Synthesis, Properties, and Applications is a unique practical reference handbook. Written by the leading experts worldwide it introduces the science of UNCD for both the R & D community and applications developers using UNCD in a diverse range of applications from m...
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Main Authors: | |
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Corporate Authors: | |
Group Author: | |
Published: |
William Andrew,
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Publisher Address: | [Place of publication not identified] : |
Publication Dates: | 2012. |
Literature type: | eBook |
Language: | English |
Edition: | Second edition. |
Series: |
Micro and Nano Technologies
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Subjects: | |
Online Access: |
http://www.sciencedirect.com/science/book/9781437734652 |
Summary: |
Ultrananocrystalline Diamond: Synthesis, Properties, and Applications is a unique practical reference handbook. Written by the leading experts worldwide it introduces the science of UNCD for both the R & D community and applications developers using UNCD in a diverse range of applications from macro to nanodevices, such as energy-saving ultra-low friction and wear coatings for mechanical pump seals and tools, high-performance MEMS/NEMS-based systems (e.g. in telecommunications), the next generation of high-definition flat panel displays, in-vivo biomedical implants, and biosensors. This work brings together the basic science of nanoscale diamond structures, with detailed information on ultra-nanodiamond synthesis, properties, and applications. The book offers discussion on UNCD in its two forms, as a powder and as a chemical vapor deposited film. Also discussed are the superior mechanical, tribological, transport, electrochemical, and electron emission properties of UNCD for a wide range of applications including MEMS/ NEMS, surface acoustic wave (SAW) devices, electrochemical sensors, coatings for field emission arrays, photonic and RF switching, biosensors, and neural prostheses, etc. Ultrananocrystalline Diamond summarises the most recent developments in the nanodiamond field, and presents them in a way that will be useful to the R & D community in both academic and corporate sectors. Coverage of both nanodiamond particles and films make this a valuable resource for both the nanotechnology community and the field of thin films / vacuum deposition. Written by the world's leading experts in nanodiamond, this second edition builds on its predecessor's reputation as the most up-to-date resource in the field. |
Item Description: | Title from publisher's Web site; (ScienceDirect; viewed on Sept. 6, 2012). |
Carrier Form: | 1 online resource (558 pages) : color illustrations. |
Bibliography: | Includes bibliographical references and index. |
ISBN: |
9781437734669 1437734669 |
Index Number: | TP873 |
CLC: | TQ164.8 |
Contents: |
Front Cover; Ultrananocrystalline Diamond; Copyright Page; Contents; Preface; List of Contributors; 1 Advances in Synthesis and Processing; 1 Stability of Diamond at the Nanoscale; 1.1 Introduction: phase stability of carbon; 1.2 Nanocarbon phase diagrams; 1.3 Structure, stability, and morphology; 1.3.1 Computational modeling of diamond nanoparticles; 1.3.2 Theoretical modeling of nanocarbon particles; 1.3.3 Coexistence of nanocarbon particles; 1.4 Stability in response to external stimuli; 1.4.1 Annealing and thermal activation; 1.4.2 Pressure- and irradiation-induced transformations. 1.4.3 Stability under induced anionic and cationic charge1.5 Surface passivation and functionalization; 1.5.1 Passivation and functionalization in oxygen-rich environments; 1.5.2 Passivation and functionalization in nitrogen-rich environments; 1.6 Impurities, dopants, and functional defects; 1.6.1 Intrinsic defects; 1.6.2 Incidental impurities; 1.6.3 Deliberate dopants; 1.6.4 Optical centers and functional defects; 1.7 Stability of quasi-1D nanocarbon; 1.7.1 Morphology of diamond nanorods and nanowires; 1.7.2 Hybrid 1D structures; 1.8 Conclusions; Acknowledgments; References. 2 Advances in Plasma Synthesis of UNCD Films2.1 Introduction and historical development of UNCD films; 2.2 UNCD growth: theory, modeling, and diagnostics; 2.2.1 Plasma discharge region; 2.2.2 Species arriving at the growth surface; 2.2.3 Growth at the surface: high renucleation rate for UNCD; 2.3 Scaling up the MPACVD process: large-area UNCD synthesis using a floating substrate holder; 2.3.1 Background; 2.3.2 Experimental description and methodologies; 2.3.3 Reactor operating road maps; 2.3.4 Experimental procedures and results; 2.4 Hot-filament CVD UNCD synthesis. 2.4.1 First report and principle of HFCVD diamond synthesis2.4.2 Scaling and current reactor technology; 2.4.3 Nanocrystalline diamond versus UNCD; 2.4.4 HFCVD (U)NCD synthesis; 2.5 Summary; Acknowledgments; References; 3 Theoretical Studies of UNCD Properties; 3.1 Introduction; 3.2 Computational methodologies; 3.2.1 Classical MD simulations; 3.2.2 DFTB calculations; 3.3 Bulk properties of UNCD; 3.3.1 UNCD model generation; 3.3.2 Structure of GBs; 3.3.3 Vibrational spectra; 3.3.4 Specific heat and Debye temperature; 3.3.5 Thermal stability and the effect of annealing on sp2/sp3 composition. 3.4 Surface properties: CNT-diamond hybrid nanomaterials3.5 Concluding remarks; Acknowledgment; References; 4 n-Type Nanocrystalline Diamond Films: Synthesis, Structure, Composition, Properties, and Applications; 4.1 Introduction; 4.2 n-type (nitrogen) carbon materials; 4.3 Synthesis of n-type NCD films; 4.3.1 Synthesis and growth mechanism; 4.4 Structural and compositional analysis of n-type NCD/UNCD; 4.5 Physical and chemical properties of n-type NCD/UNCD; 4.5.1 Electronic properties (transport, FE, and thermal conductivity); Transport properties; Electron field emission. |