Screen LibraryThe chemistry of pyrroles /
The Chemistry of Pyrroles, Volume 34 aims to provide a comprehensive survey of the synthesis of simple pyrroles and to present, wherever possible, a mechanistic and theoretical rationale for the multitude of reactions known for pyrroles. The book discusses the structure and reactivity of pyrrole; th...
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| Main Authors: | |
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| Corporate Authors: | |
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| Published: |
Academic Press,
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| Publisher Address: | London ; New York : |
| Publication Dates: | 1977. |
| Literature type: | eBook |
| Language: | English |
| Series: |
Organic chemistry : a series of monographs ;
volume 34 |
| Subjects: | |
| Online Access: |
http://www.sciencedirect.com/science/bookseries/18745954/34 |
| Summary: |
The Chemistry of Pyrroles, Volume 34 aims to provide a comprehensive survey of the synthesis of simple pyrroles and to present, wherever possible, a mechanistic and theoretical rationale for the multitude of reactions known for pyrroles. The book discusses the structure and reactivity of pyrrole; the synthesis of the pyrrole ring; and the electrophilic substitution of the pyrrole ring. The text also describes the oxidation and reduction of the pyrrole ring; the rearrangement and addition reactions; and the ketones, aldehydes, and carboxylic acid derivatives of pyrrole. Alkylpyrroles and relate. |
| Carrier Form: | 1 online resource (ix, 525 pages) : illustrations. |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: |
9781483218472 1483218473 |
| Index Number: | QD401 |
| CLC: | O626.13 |
| Contents: |
Front Cover; The Chemistry of Pyrroles; Copyright Page; Foreword; Abbreviations and Nomenclature; Table of Contents; Chapter 1. INTRODUCTION; References; Chapter 2. THE STRUCTURE AND REACTIVITY OF PYRROLE; A. Molecular and Electronic Structure of Pyrrole; B. Aromaticity and Resonance Energy; C. Molecular Orbital Calculations on Pyrroles; D. Theoretical Treatment of the Reactivity of Pyrrole with Electrophiles; References; Chapter 3. THE SYNTHESIS OF THE PYRROLE RING; A. Introduction; B. 2+2 Carbon Units; C. 1+3 Carbon Units; D. From Four Carbon Units; E. Ring-contractions F. Miscellaneous ReactionsReferences; Chapter 4. ELECTROPHILIC SUBSTITUTION OF THE PYRROLE RING; A. Introduction; B. Protonation of the Pyrrole Ring; C. Nitration and Nitrosation; D. Halogenation; E. C-Alkylation Reactions; F. C-Acylation Reactions; G. Reactions with Carbonyl Compounds; H. Reactions of the Pyrryl Anion; I. Miscellaneous Electrophilic Reactions; J. Summary of the Reactivity of Pyrrole and Orientation Effects of Substituents; References; Chapter 5. OXIDATION AND REDUCTION OF THE PYRROLE RING; A. The Reactions of Pyrroles with Molecular Oxygen; B. Oxidation by Chemical Reagents C. Anodic Oxidation of PyrrolesD. Reduction of the Pyrrole Ring; References; Chapter 6. REARRANGEMENT AND ADDITION REACTIONS; A. Thermal Rearrangements retaining the Pyrrole Ring; B. Photochemical Rearrangements retaining the Pyrrole Ring; C. Addition Reactions; D. Reactions with Radicals; References; Chapter 7. KETONES, ALDEHYDES AND CARBOXYLIC ACID DERIVATIVES OF PYRROLE; A. Resonance Interaction between the Pyrrole Ring and the Carbonyl Substituent; B. Chemical Reactivity; References; Chapter 8. ALKYLPYRROLES AND RELATED COMPOUNDS; B. Chemical Reactivity; C. Silylpyrroles D. Pyrrolophanes and other Bridged PyrrolesReferences; A. Tautomerism; Chapter 9. HYDROXY- AND AMINOPYRROLES AND RELATED COMPOUNDS; A. Tautomerism; B. Synthesis; C. Chemical Reactivity; D. Pyrrylthiols; References; Chapter 10. AZAFULVENES; A. Structure and Reactivity; B. Synthesis; C. Spectroscopic Properties; References; Chapter 11. PHYSICO-ORGANIC PROPERTIES OF PYRROLE; A. Molecular Association; B. Basicity and Acidity Measurements; C. Dipole Moments; D. Polarographic Properties; E. Electronic Spectra; F. IR and Raman Spectra; G. NMR Spectra; H. Mass Spectra; References; Index |