Screen LibrarySulphones in organic synthesis /
Over the last twenty years the use of sulphones in organic synthesis has increased dramatically, the synthetic repertoire of sulphones having been developed to such an extent as to rival the carbonyl functionality for versatility. Not only have sulphones been employed in a great many synthetic metho...
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| Main Authors: | |
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| Corporate Authors: | |
| Published: |
Pergamon,
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| Publisher Address: | Oxford [England] ; New York : |
| Publication Dates: | 1993. |
| Literature type: | eBook |
| Language: | English |
| Edition: | First edition. |
| Series: |
Tetrahedron organic chemistry series ;
v. 10 |
| Subjects: | |
| Online Access: |
http://www.sciencedirect.com/science/bookseries/14601567/10 |
| Summary: |
Over the last twenty years the use of sulphones in organic synthesis has increased dramatically, the synthetic repertoire of sulphones having been developed to such an extent as to rival the carbonyl functionality for versatility. Not only have sulphones been employed in a great many synthetic methodologies, enabling the preparation of a vast array of functionalised products, but the sulphone group has also proved to be of enormous value in many of the most demanding and sophisticated total syntheses carried out in recent years. This book describes in detail all of the important sulphone chemi. |
| Carrier Form: | 1 online resource (xi, 381 pages) : illustrations. |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: |
9781483292793 1483292797 |
| Index Number: | QD305 |
| CLC: | O621.3 |
| Contents: |
Front Cover; Sulphones in Organic Synthesis; Copyright Page; Preface; Table of Contents; CHAPTER 1. Introduction to Sulphone Chemistry; References; CHAPTER 2. The Preparation of Sulphones; 2.1 Simple Alkyl Aryl and Dialkyl Sulphones; 2.2 Vinyl Sulphones; 2.3 Allylic, Allenic, Alkynyl and Aryl Sulphones; 2.4 Functionalised Sulphones; CHAPTER 3. Sulphonyl Carbanions; 3.1 Introduction to Sulphonyl Carbanions; 3.2 Reactions of Simple Sulphonyl Carbanions; 3.3 Reactions of Additionally Stabilised Sulphonyl Carbanions; 3.4 Sulphonyl Polyanions; CHAPTER 4. Additions to Unsaturated Sulphones. 4.1 Heteroatom Nucleophiles4.2 Non-stabilised Organometallics; 4.3 Enolates, Related Anions and Miscellaneous Carbon Nucleophiles; 4.4 Cyclopropanations; 4.5 Radical Additions; CHAPTER 5. Rearrangements of Sulphones; 5.1 Ring Expansions and Fragmentations; 5.2 Sulphinate to Sulphone Rearrangements; 5.3 1,3-Rearrangements of Allylic Sulphones; 5.4 The Truce-Smiles Rearrangement; 5.5 Miscellaneous Rearrangements; CHAPTER 6. Cycloaddition Chemistry of Unsaturated Sulphones; 6.1 [2+2] Cycloadditions; 6.2 [3+2] Cycloadditions; 6.3 [4+2] Cycloadditions. CHAPTER 7. Carbon-Carbon Double-Bond Formation by Sulphone Elimination7.1 The Julia Olefination Reaction; 7.2 Alternative -Eliminations of Sulphones; 7.3 The Ramberg-Ba cklund Reaction; CHAPTER 8. Chemistry of Cyclic Sulphones; 8.1 Three-membered Ring Sulphones; 8.2 Four-membered Ring Sulphones; 8.3 Five-membered Ring Sulphones; 8.4 Functionalised Normal-sized Rings; 8.5 Larger Ring Sulphones; CHAPTER 9. Desulphonylation; 9.1 Simple Alkyl Aryl and Dialkyl Sulphones; 9.2 Allylic Sulphones; 9.3 Vinyl Sulphones; 9.4 Functionalised Sulphones; 9.5 Sulphone Reduction; INDEX. |