Screen LibraryReactive intermediate chemistry
"Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental area of organic chemistry. Intended as a free-standing resource for the entire chemical community, it should be especially useful for graduate students as a primary or supplemental textbook. This vo...
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| Group Author: | ; ; |
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| Published: |
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| Literature type: | Electronic eBook |
| Language: | English |
| Subjects: | |
| Online Access: |
http://onlinelibrary.wiley.com/book/10.1002/0471721492 |
| Summary: |
"Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental area of organic chemistry. Intended as a free-standing resource for the entire chemical community, it should be especially useful for graduate students as a primary or supplemental textbook. This volume features a "three-dimensional" approach in which reactive intermediates are considered by class, the kinetic realms they inhabit, and in historical context, connecting the older, product-based chemistry with contemporary direct observational and computational approaches. Reactive Intermediate Chemistry is a reference for the student or professional in academic, pharmaceutical, or industrial laboratories."--Jacket. |
| Carrier Form: | 1 online resource (viii, 1072 pages) : illustrations |
| Bibliography: | Includes bibliographical references and index. |
| ISBN: |
9780471721499 (electronic bk.) 0471721492 (electronic bk.) 0471233242 (acid-free paper) 9780471233244 (acid-free paper) 1280556951 9781280556951 |
| Index Number: | QD502 |
| CLC: | O643.1 |
| Contents: |
Carbocations / Crossing the borderline between SN1 and SN2 nucleophilic substitution at aliphatic carbon / Carbanions / Radicals / Non-kekulé molecules as reactive intermediates / Organic radical ions / Singlet carbenes / Stable singlet carbenes / Triplet carbenes / Atomic carbon / Nitrenes / Synthetic carbene and nitrene chemistry / Nitrenium ions / Silylenes (and germylenes, stannylenes, plumbylenes) / Strained hydrocarbons: structures, stability, and reactivity / Arynes / Matrix isolation / Nanosecond laser flash photolysis: a tool for physical organic chemistry / The picosecond realm / Reactions on the femtosecond time scale / Potential energy surfaces and reaction dynamics / The partnership between electronic structure calculations and experiments in the study of reactive intermediates / |