A guide to chalcogen-nitrogen chemistry /
Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Such studies have both fundamental and practical importance. A Guide to Chalcogen-Nitrogen Chemistry examines the role of chalcogen-nitrogen compounds in area...
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Main Authors: | |
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Corporate Authors: | |
Published: |
World Scientific Pub. Co.,
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Publisher Address: | Singapore ; Hackensack, N.J. : |
Publication Dates: | 2005. |
Literature type: | eBook |
Language: | English |
Subjects: | |
Online Access: |
http://www.worldscientific.com/worldscibooks/10.1142/5701#t=toc |
Summary: |
Chalcogen-nitrogen chemistry involves the study of compounds that exhibit a linkage between nitrogen and sulfur, selenium or tellurium atoms. Such studies have both fundamental and practical importance. A Guide to Chalcogen-Nitrogen Chemistry examines the role of chalcogen-nitrogen compounds in areas ranging from solid-state inorganic chemistry to biochemistry. The discussion covers fundamental questions concerning the bonding in electron-rich systems, as well as potential practical applications of polymers and materials with novel magnetic or electrical properties. This book is the only acc |
Carrier Form: | 1 online resource (xix,318pages) : illustrations |
Bibliography: | Includes bibliographical references and index. |
ISBN: | 9789812563118 (electronic bk.) |
CLC: | O612.6 |
Contents: |
1. Introduction. 1.1. General considerations. 1.2. Binary species. 1.3. Cyclic chalcogen imides. 1.4. Organic derivatives. 1.5. Unsaturated sulfur - nitrogen ring systems. 1.6. Intramolecular [symbol]-[symbol] interactions. 1.7. Intramolecular [symbol]-[symbol] interactions. 1.8. Chalcogen-nitrogen chains and polymers. 1.9. Chalcogen-nitrogen compounds with the chalcogen in a higher oxidation state -- 2. Formation of chalcogen-nitrogen bonds. 2.1. From ammonia and ammonium salts. 2.2. From amines and amido-lithium or sodium reagents. 2.3. From azides. 2.4. From silicon-nitrogen or tin-nitrog 9. Chalcogen-nitrogen oxides. 9.1. Introduction. 9.2. The thionyl imide anion, [NSO][symbol]. 9.3. The thionitrite and perthionitrite anions, [SNO][symbol] and [SSNO][symbol]. 9.4. The [SO[symbol]N[symbol]][symbol] anions (x = 2, 3). 9.5. Bis(sulfinylamino)chalcogenanes, E(NSO)[symbol] (E = S, Se, Te). 9.6. Organic chalcogenylamines, RNEO (E = S, Se, Te). 9.7. S-nitrosothiols. 9.8. Cyclic chalcogen-nitrogen oxides -- 10. Acyclic organochalcogen-nitrogen compounds. 10.1. Introduction. 10.2. Chalcogenonitrosyls, RNE (E = S, Se). 10.3. N-thiosulfinylamines, RNSS. 10.4. Chalcogen diimides, RN=E= |