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Author: jointly organized by the International Atomic Energy Agency and the Food and Agriculture Organization of the United Nations

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Photochemically-generated intermediates in synthesis /

This book fills a gap between physical organic photochemistry and photochemistry applied to organic synthesis. It focuses on photoreactions involving an intermediate that has been (or at least may be) generated and where mechanistic aspects control the course of a reaction and its synthetic value. T...

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Bibliographic Details
Main Authors: Albini, Angelo
Group Author: Fagnoni, Maurizio
Published: John Wiley & Sons, Inc.,
Publisher Address: Hoboken, New Jersey :
Publication Dates: [2013]
Literature type: eBook
Language: English
Subjects:
Carbocations.
Carbanions.
Intermediates (Chemistry)
Photochemistry.
SCIENCE > Organic. > Organic.
Organische Synthese
Zwischenstufe.
Photochemische Reaktion
Radikal.
Electronic books.
Online Access: http://onlinelibrary.wiley.com/book/10.1002/9781118689202
Summary: This book fills a gap between physical organic photochemistry and photochemistry applied to organic synthesis. It focuses on photoreactions involving an intermediate that has been (or at least may be) generated and where mechanistic aspects control the course of a reaction and its synthetic value. The first chapter presents general aspects, and each of the following chapters contains a short introduction with the key kinetic data for typical intermediates and reference to mechanistic work. The sections of each chapter then consider the various aspects of the topics: radicals, cations, carbenes, and nitrenes.
Carrier Form: 1 online resource.
Bibliography: Includes bibliographical references and index.
ISBN: 9781118689301 (epub)
1118689305 (epub)
9781118689141 (pdf)
1118689143 (pdf)
9781118689332 ( mobi)
111868933X ( mobi)
9781118689202
1118689208
Index Number: QD305
CLC: O644.1
Contents: Photogenerated intermediates : principles and practice -- Photogeneration of carbon centered radicals -- Photogeneration of heteroatom-centered radicals -- Photogeneration of biradicals and radical pairs -- Photochemical generation of radical ions -- Photogeneration of carbocations and carbanions -- Photogeneration of carbenes and nitrenes -- Manipulating intermediates the photochemical way.

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