Photoactive inorganic nanoparticles : surface composition and nanosystem functionality /

Nanoparticles are usually designed for specific applications and selection of the most convenient capping can be a complex task, but is crucial for successful design. In this volume, the authors discuss the selection of functional cappings to coat nanoparticles in a range of different applications....

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Bibliographic Details
Corporate Authors: Elsevier Science & Technology.
Group Author: P erez Prieto, Julia; Gonz alez B ejar, Mar ia
Published: Elsevier,
Publisher Address: Amsterdam, Netherlands :
Publication Dates: [2019]
Literature type: eBook
Language: English
Series: Micro & nano technologies series
Subjects:
Online Access: https://www.sciencedirect.com/science/book/9780128145319
Summary: Nanoparticles are usually designed for specific applications and selection of the most convenient capping can be a complex task, but is crucial for successful design. In this volume, the authors discuss the selection of functional cappings to coat nanoparticles in a range of different applications. The opening chapter provides an understanding of basic aspects of surface chemistry at the nanoscale. Each following chapter covers a particular kind of capping, beginning with a basic introduction and describing characteristics such as structure, functionality, solubility, (photo)physics, and toxicity. Special emphasis is placed on how important these specific features are in the preparation of smart nanomaterials. In-depth explanations and examples are then presented, highlighting the latest results and cutting-edge research carried out with the selected capping according to the kind of nanoparticle employed (such as rare-earth doped, semiconducting, and metallic). An additional chapter focusses on computational techniques for modelling nanosurfaces. Photoactive Inorganic Nanoparticles: Surface Composition and its Role in Nanosystem Functionality will be a valuable working resource for graduate students, researchers, and industry R & D professionals working in the field of applied nanomaterials.
Carrier Form: 1 online resource (1 volume).
Bibliography: Includes bibliographical references and index.
ISBN: 9780128145326
0128145323
Index Number: QC611
CLC: O462.3
Contents: Front Cover; Photoactive Inorganic Nanoparticles; Copyright Page; Contents; List of contributors; Preface; Acknowledgment; 1 Fundamental concepts on surface chemistry of nanomaterials; 1.1 Introduction; 1.2 Physical chemistry of the association of molecules to nanoparticles; 1.3 Corona formation and its role in surface composition; 1.4 General considerations for evaluating association of molecules to nanostructures; 1.5 Role of colloidal stability in nanoparticle-binding capabilities; 1.6 General considerations on measuring association of molecules to nanoparticles
1.7 Nanoparticle concentration and polydispersity1.8 Conclusions and outlook; Acknowledgments; References; 2 Computational modeling of the adsorption of capping agent biomolecules to inorganic nanoparticles; 2.1 Modeling in biomolecules and inorganic nanoparticles adsorption: past and present; 2.2 Using molecular dynamics to characterize nanoparticle surface adsorption of capping agents; 2.3 Computational modeling of adsorption: challenges and new methods to understand the adsorption of capping agents to inor ... ; References
3 Near-infrared photochemistry assisted by upconverting nanoparticles3.1 Introduction; 3.1.1 Upconverting nanoparticles; 3.2 Upconverting nanoparticles-assisted photochemistry; 3.3 Upconverting nanoparticle-assisted organic photochemistry; 3.4 Upconverting nanoparticles-assisted inorganic photochemistry; 3.5 Conclusions; Acknowledgments; References; 4 Dressing up for the occasion: the many faces of decorated titanium dioxide in photocatalysis; 4.1 Introduction; 4.2 Photocatalytic activity of TiO2; 4.3 Modification of the photocatalytic activity of TiO2; 4.3.1 TiO2 doping
4.3.2 TiO2 decoration4.4 TiO2 in solar cells; 4.5 Photocatalytic activity of decorated TiO2 as an aid for organic transformations; 4.5.1 TiO2-mediated photoreductions; 4.5.2 TiO2-mediated photooxidations; 4.5.3 C-C couplings; 4.5.4 Cyclizations; 4.5.5 TiO2 catalysts for hydrogen generation; 4.6 Sunscreens based on TiO2; Acknowledgments; References; 5 Nanoparticles within functional frameworks and their applications in photo(electro)catalysis; 5.1 Introduction; 5.2 Synthesis methods; 5.2.1 Sol-gel method; 5.2.2 Solvothermal method; 5.2.3 Mechanochemical method; 5.2.4 Sonochemical method
5.3 Structures of the functional frameworks5.3.1 Encapsulation of nanoentities in metal organic frameworks; 5.3.2 Core-shell and hollow structure materials; 5.3.3 Layer-by-layer structure materials; 5.3.4 Surface-modified materials; 5.3.5 Composite materials; 5.4 Applications in photocatalysis; 5.5 Applications in photoelectrocatalysis; 5.6 Conclusions; Acknowledgments; References; 6 Photoactive nanoparticles capped with macrocycles as platforms and hosts; 6.1 Pillararene-capped nanoparticles; 6.1.1 Quantum dots; 6.1.2 Gold and silver nanoparticles; 6.2 Calixarene-capped nanoparticles