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Experimental methods in kinetic studies /

This book is a guide to kinetic studies of reaction mechanisms. It reviews conventional reactor types and data collection methods, and introduces a new methodology for data collection using Temperature Scanning Reactors (TSR). It provides a theoretical and practical approach to temperature scanning...

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Bibliographic Details
Main Authors: Wojciechowski, Bohdan W., 1935- (Author)
Corporate Authors: Elsevier Science & Technology.
Group Author: Rice, N. M.
Published: Elsevier,
Publisher Address: Amsterdam ; Boston :
Publication Dates: 2003.
Literature type: eBook
Language: English
Edition: Revised edition.
Subjects:
Chemical kinetics.
SCIENCE > Physical & Theoretical. > Physical & Theoretical.
Electronic books.
Online Access: http://www.sciencedirect.com/science/book/9780444513144
Summary: This book is a guide to kinetic studies of reaction mechanisms. It reviews conventional reactor types and data collection methods, and introduces a new methodology for data collection using Temperature Scanning Reactors (TSR). It provides a theoretical and practical approach to temperature scanning (TS) methodology and supports a revival of kinetic studies as a useful approach to the fundamental understanding of chemical reaction mechanisms and the consequential reaction kinetics. Describes a new patented technology Of interest to industrial and academic researchers in the fields of kinetics and catalysis No existing competitor for this title.
Carrier Form: 1 online resource (xii, 310 pages) : illustrations
Bibliography: Includes bibliographical references (pages 303-306) and index.
ISBN: 9780444513144
0444513140
9780080531366
0080531369
Index Number: QD502
CLC: O643.1
Contents: 1. Reactor Types and their Characteristics -- 2. Collecting Data under Isothermal Operation -- 3. Using Kinetic Data in Reaction Studies -- 4. Difficulties with Mechanistic Rate Expressions -- 5. The Theory of Temperature Scanning Operation -- 6. Verification of Kinetic Dominance -- 7. Processing of Data -- 8. Fitting Rate Expressions to TSR Data -- 9. Interpretation of Rate Parameters -- 10. Statistical Evaluation of Multiparameter Fits -- 11. Experimental Studies Using TSR Methods -- 12. Using a Mechanistic Rate Expression -- 13. TSR Hardware Configurations -- References -- Index.

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