Experimental methods in kinetic studies /
This book is a guide to kinetic studies of reaction mechanisms. It reviews conventional reactor types and data collection methods, and introduces a new methodology for data collection using Temperature Scanning Reactors (TSR). It provides a theoretical and practical approach to temperature scanning...
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Main Authors: | |
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Published: |
Elsevier,
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Publisher Address: | Amsterdam ; Boston : |
Publication Dates: | 2003. |
Literature type: | eBook |
Language: | English |
Edition: | Revised edition. |
Subjects: | |
Online Access: |
http://www.sciencedirect.com/science/book/9780444513144 |
Summary: |
This book is a guide to kinetic studies of reaction mechanisms. It reviews conventional reactor types and data collection methods, and introduces a new methodology for data collection using Temperature Scanning Reactors (TSR). It provides a theoretical and practical approach to temperature scanning (TS) methodology and supports a revival of kinetic studies as a useful approach to the fundamental understanding of chemical reaction mechanisms and the consequential reaction kinetics. Describes a new patented technology Of interest to industrial and academic researchers in the fields of kinetics and catalysis No existing competitor for this title. |
Carrier Form: | 1 online resource (xii, 310 pages) : illustrations |
Bibliography: | Includes bibliographical references (pages 303-306) and index. |
ISBN: |
9780444513144 0444513140 9780080531366 0080531369 |
Index Number: | QD502 |
CLC: | O643.1 |
Contents: | 1. Reactor Types and their Characteristics -- 2. Collecting Data under Isothermal Operation -- 3. Using Kinetic Data in Reaction Studies -- 4. Difficulties with Mechanistic Rate Expressions -- 5. The Theory of Temperature Scanning Operation -- 6. Verification of Kinetic Dominance -- 7. Processing of Data -- 8. Fitting Rate Expressions to TSR Data -- 9. Interpretation of Rate Parameters -- 10. Statistical Evaluation of Multiparameter Fits -- 11. Experimental Studies Using TSR Methods -- 12. Using a Mechanistic Rate Expression -- 13. TSR Hardware Configurations -- References -- Index. |